CPE134060 HYDRAZINE SOLUTION 70%

Product and Company Identification
Composition/Information on Ingredients
Hazards Identification
First Aid Measures
Fire Fighting Measures
Accidental Release Measures
Handling and Storage
Exposure Controls/Personal Protection
Physical and Chemical Properties
Stability and Reactivity
Toxicological Information
Ecological Information
Disposal Considerations
Transport Information
Regulatory Information
Other Information / Hazmat Info / Hazcom Label

MSDS Safety Information

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FSC:

9135

NIIN:

01-049-9592

MSDS Date:

01/01/1995

MSDS Num:

BXNYT

Submitter:

F BT

Tech Review:

07/24/1995

Status CD:

C

Product ID:

CPE134060 HYDRAZINE SOLUTION 70%

MFN:

03

Article:

N

Kit Part:

N

Responsible Party

Cage:

8X135

Name:

OLIN CORP

Address:

120 LONG RIDGE RD

Box:

1355

City:

STAMFORD

State:

CT

Zip:

06904-1355

Country:

US

Info Phone Number:

203-356-3449

Emergency Phone Number:

203-356-3449

Preparer's Name:

N/P

Proprietary Ind:

N

Review Ind:

Y

Published:

Y

Special Project CD:

N

Preparer Co. when other than Responsible Party Co.

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Cage:

8X135

Assigned Ind:

N

Name:

OLIN CORP

Address:

51 CORPORATE WOODS 9393 W 110 ST

Box:

N/K

City:

OVERLAND PARK

State:

KS

Zip:

66210

Contractor Summary

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Cage:

8X135

Name:

OLIN CORP

Address:

51 CORPORATE WOODS 9393 W 110 ST

Box:

N/K

City:

OVERLAND PARK

State:

KS

Zip:

66210

Country:

US

Phone:

800-432-6546

Cage:

99530

Name:

OLIN CORPORATION

Address:

501 MERRITT 7

Box:

4500

City:

NORWALK

State:

CT

Zip:

06856-4500

Country:

US

Phone:

800-511-6737/203-356-3449

= Item Description Information =

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Item Manager:

FPH

Item Name:

PROPELLANT,HYDRAZINE-WATER

Specification Number:

NK

Type/Grade/Class:

NK

Unit of Issue:

LB

Quantitative Expression:

NK

UI Container Qty:

NK

Type of Container:

Ingredients

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Cas:

 302-01-2

Code:

 M

RTECS #:

 MU7175000

Code:

 M

Name:

 HYDRAZINE INTENDED CHANGE (IC) = 0.01 MG/CUM

% Text:

70

Environmental Wt:

Other REC Limits:

N/K

OSHA PEL:

0.1 PPM

Code:

M

OSHA STEL:

Code:

ACGIH TLV:

0.1 PPM

Code:

M

ACGIH STEL:

N/P

Code:

EPA Rpt Qty:

1 LB

DOT Rpt Qty:

1 LB

Ozone Depleting Chemical:

N

Cas:

 7732-18-5

Code:

 M

RTECS #:

 ZC0110000

Code:

 M

Name:

 WATER

% Text:

30

Environmental Wt:

Other REC Limits:

N/K

OSHA PEL:

N/K

Code:

M

OSHA STEL:

Code:

ACGIH TLV:

N/K

Code:

M

ACGIH STEL:

N/P

Code:

EPA Rpt Qty:

DOT Rpt Qty:

Ozone Depleting Chemical:

N

Health Hazards Data

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LD50 LC50 Mixture

ORAL LD50 (RAT): 90 MG/KG

Route Of Entry Inds - Inhalation:

YES

Skin:

YES

Ingestion:

YES

Carcinogenicity Inds - NTP:

NO

IARC:

NO

OSHA:

NO

Health Hazards Acute And Chronic

INHALATION: NOSE/THROAT/UPPER RESPIRATORY TRACT/LUNG IRRITATION, PULMONARY EDEMA, LUNG/LIVER/KIDNEY/BLOOD/CNS DAMAGE, HEMOLYSIS OF BLOOD CELLS. SKIN: SEVERE IRRITATION/BURNS/DERMATITIS. EYES: BURNS/PERMANENT CORNEAL DAMAGE. INGESTION: GI TR ACT IRRITATIONBURNS. HYDRAZINE IS CONSIDERED MUTAGENIC, A SENSITIZER & TOXIC.

Explanation Of Carcinogenicity

NONE

Signs And Symptions Of Overexposure

IRRITATION, INFLAMMATION, BRONCHITIS, VOMITING, DIARRHEA, DIZZINESS, CYANOSIS, CONVULSIONS, ALLERGIC REACTION, RASH, SWELLING, REDNESS, DISCHARGE, TEMPORARY BLINDNESS, ABDOMINAL PAIN, BLEEDING, TISSUE ULCERATION.

Medical Cond Aggravated By Exposure

LIVER/KIDNEY/BLOOD/CARDIOVASCULAR DISEASE & ASTHMA.

First Aid Information

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EYES/SKIN: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. INGESTION: IMMEDIATELY DRINK LARGE AMOUNTS OF WATER. INDUCE VOMITING. DON'T GIVE ANYTHING BY MOUTH IF UNCONSCIOUS/CONVULSIVE. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGE N IF NEEDED. EEP WARM & QUIET. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Spill Release Procedures

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EVACUATE AREA/REMOVE IGNITION SOURCES/STOP SOURCE. AIR: SUPPRESS VAPORS W/WATER FOG. CONTAIN LIQUID FOR TREATMENT/DISPOSAL AS HAZARDOUS WASTE. WATER: SAFELY DIVERT WATER FLOW AROUND AREA. LAND: DIKE/TRENCH TO CONTAIN. DILUTE TO 10% W/WATER. (SUPP)

Neutralizing Agent

5-8% CALCIUM HYPOCHLORITE SOLUTION.

Waste Disposal Methods

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AS HAZARDOUS LIQUID WASTE, MUST BE DISPOSED OF IAW/FEDERAL, STATE & LOCAL REGULATIONS IN PERMITTED HAZARDOUS WASTE TREATMENT/STORAGE/DISPOSAL FACILITY BY INCINERATION. CONTAINERIZE & LABEL ALL SPILL MATERIALS PROPERLY. CORROSIVE UN2927.

Handling and Storage Precautions

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STORE IN WELL VENTILATED AREA AWAY FROM IGNITION SOURCES. DON'T STORE >124F, EXPOSE TO DIRECT LIGHT. MAINTAIN INERT ATMOSPHERE OVER SOLUTION ALWAYS.

Other Precautions

DON'T CONTAMINATE. TRANSFER LINES & PIPING SHOULD BEELECTRICALLY GROUNDED. RETEST MATERIAL >5 YEARS OLD BEFORE USE. AVOIDCONTACT W/SKIN/EYES/CLOTHING. PACKAGE ONLY IN TEFLON/HIGH DENSITYPOLYETHYLENE/304L/347 STAINLESS STEEL.

Fire and Explosion Hazard Information

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Flash Point Method:

COC

Flash Point:

Flash Point Text:

147F

Autoignition Temp:

Autoignition Temp Text:

N/A

Lower Limits:

4.7

Upper Limits:

100

Extinguishing Media

WATER SPRAY.

Fire Fighting Procedures

USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. WEAR A POSITIVE PRESSURE SELF CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING.

Unusual Fire/Explosion Hazard

ABSORPTION OF HYDRAZINE SOLUTION BY RAGS/COTTON WASTE/SAWDUST/SIMILAR ORGANIC MATERIALS CAN RESULT IN SPONTANEOUS COMBUSTION. AUTO-IGNITION TEMP: 518F.

Control Measures

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Respiratory Protection

WEAR A NIOSH/MSHA APPROVED FULL-FACE POSITIVE PRESSURE SUPPLIED AIR RESPIRATOR IF ANY EXPOSURE OCCURS.

Ventilation

LOCAL EXHAUST TO MAINTAIN LEVELS <TLV.

Protective Gloves

BUTYL RUBBER

Eye Protection

SAFETY GLASSES & FACE SHIELD

Other Protective Equipment

BUTYL RUBBER BOOTS/APRON/PROTECTIVE SUIT, EYE WASH, SAFETY SHOWER.

Work Hygienic Practices

REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH AFTER HANDLING. RINSE LEATHER ARTICLES W/WATER & DISCARD THEM.

Supplemental Safety and Health

PH (1% SOLUTION): 10.1-10.7. INCOMPATIBLES: IRON/COPPER/LEAD/MANGANESE/MOLYBDENUM/ORGANIC MATERIALS. SPILLS: NEUTRALIZE DILUTED HYDRAZINE. DON'T ADD DRY CALCIUM HYPOCHLORITE DUE TO VIOLENT REACTION. ABSORB NEUTRALIZED MATERIAL W/CLAY/SAND/C OMMERCIAL ABSOBENT. DECONTAMINATE AREA W/STRONG DETERGENT & FLUSH W/MUCH WATER.

Physical/Chemical Properties

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HCC:

NRC/State LIC No:

Net Prop WT For Ammo:

 

 

Boiling Point:

B.P. Text:

246F

Melt/Freeze Pt:

M.P/F.P Text:

-55F

Decomp Temp:

Decomp Text:

518F

Vapor Pres:

14

Vapor Density:

N/K

Volatile Org Content %:

Spec Gravity:

1.03

VOC Pounds/Gallon:

PH:

(SUPP)

VOC Grams/Liter:

Viscosity:

N/P

Evaporation Rate & Reference:

N/K

Solubility in Water:

MISCIBLE

Appearance and Odor:

CLEAR, COLORLESS LIQUID W/AMMONIA ODOR.

Percent Volatiles by Volume:

100

Corrosion Rate:

N/K

Reactivity Data

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Stability Indicator:

YES

Stability Condition To Avoid:

TEMPS >124F & 518F AFTER WATER REMOVAL, DIRECT LIGHT, FIRE, HEAT, SPARKS, OPEN FLAME & OTHER IGNITION SOURCES.

Materials To Avoid:

STRONG OXIDIZERS/OXYGEN/HYDROGEN PEROXIDE/HALOGEN FLUORIDES/FUMING NITRIC ACID/HYPOCHLORITE SOLUTION/METAL OXIDES (SUPP)

Hazardous Decomposition Products:

AMMONIA & HYDROGEN.

Hazardous Polymerization Indicator:

NO

Conditions To Avoid Polymerization:

N/K

Toxicological Information

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Toxicological Information:

N/P

Ecological Information

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Ecological:

N/P

MSDS Transport Information

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Transport Information:

N/P

Regulatory Information

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Sara Title III Information:

N/P

Federal Regulatory Information:

N/P

State Regulatory Information:

N/P

Other Information

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Other Information:

N/P

HMIS HAZCOM Label

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Product ID:

CPE134060 HYDRAZINE SOLUTION 70%

Cage:

8X135

Assigned IND:

N

Company Name:

OLIN CORP

Street:

51 CORPORATE WOODS 9393 W 110 ST

PO Box:

N/K

City:

OVERLAND PARK

State:

KS

Zipcode:

66210

Country:

US

Health Emergency Phone:

203-356-3449

Label Required IND:

Y

Date Of Label Review:

12/16/1998

Status Code:

C

MFG Label NO:

Label Date:

12/16/1998

Year Procured:

N/K

Origination Code:

G

Chronic Hazard IND:

N/P

Eye Protection IND:

N/P

Skin Protection IND:

N/P

Signal Word:

N/P

Respiratory Protection IND:

N/P

Health Hazard:

Contact Hazard:

Fire Hazard:

Reactivity Hazard:

Hazard And Precautions

INHALATION: NOSE/THROAT/UPPER RESPIRATORY TRACT/LUNG IRRITATION, PULMONARY EDEMA, LUNG/LIVER/KIDNEY/BLOOD/CNS DAMAGE, HEMOLYSIS OF BLOOD CELLS. SKIN: SEVERE IRRITATION/BURNS/DERMATITIS. EYES: BURNS/PERMANENT CORNEAL DAMAGE. INGESTION: GI TR ACT IRRITATIONBURNS. HYDRAZINE IS CONSIDERED MUTAGENIC, A SENSITIZER & TOXIC. IRRITATION, INFLAMMATION, BRONCHITIS, VOMITING, DIARRHEA, DIZZINESS, CYANOSIS, CONVULSIONS, ALLERGIC REACTION, RASH, SWELLING, REDNESS, DISCHARGE, TEMPORARY BLI NDNESS, ABDOMINAL PAIN, BLEEDNG, TISSUE ULCERATION.

This information is derived from the Hazardous Material Information System which is utilized by the U.S. Department of Defense. IntraWEB, LLC and its Distributors in no manner whatsoever, expressly or implied warrants, states, or intends said information to have any application use or viability by or to any person or persons. Any person utilizing this information should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.